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Efficient removal of heavy metals from electroplating wastewater using polymer ligands

Md. Lutfor RAHMAN,Shaheen M. SARKAR,Mashitah Mohd YUSOFF

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 352-361 doi: 10.1007/s11783-015-0783-0

摘要： Poly(hydroxamic acid)-poly(amidoxime) chelating ligands were synthesized from poly(methyl acrylate-co-acrylonitrile) grafted acacia cellulose for removing toxic metal ions from industrial wastewaters. These ligands showed higher adsorption capacity to copper (2.80 mmol?g ) at pH 6. In addition, sorption capacities to other metal ions such as iron, zinc, chromium, and nickel were also found high at pH 6. The metal ions sorption rate (t ) was very fast. The rate of adsorption of copper, iron, zinc, chromium, nickel, cobalt, cadmium and lead were 4, 5, 7, 5, 5, 8, 9 and 11 min, respectively. Therefore, these ligands have an advantage to the metal ions removal using the column technique. We have successfully investigated the known concentration of metal ions using various parameters, which is essential for designing a fixed bed column with ligands. The wastewater from electroplating plants used in this study, having chromium, zinc, nickel, copper and iron, etc. For chromium wastewater, ICP analysis showed that the Cr removal was 99.8% and other metal ions such as Cu, Ni, Fe, Zn, Cd, Pb, Co and Mn removal were 94.7%, 99.2%, 99.9%, 99.9%, 99.5%, 99.9%, 95.6% and 97.6%, respectively. In case of cyanide wastewater, the metal removal, especially Ni and Zn removal were 96.5 and 95.2% at higher initial concentration. For acid/alkali wastewater, metal ions removing for Cd, Cr and Fe were 99.2%, 99.5% and 99.9%, respectively. Overall, these ligands are useful for metal removal by column method from industrial wastewater especially plating wastewater.

关键词： heavy metals     adsorption     wastewater     chelating ligands     plating industry    

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Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy

Fatih Ilhan, Kubra Ulucan-Altuntas, Yasar Avsar, Ugur Kurt, Arslan Saral

《环境科学与工程前沿（英文）》 2019年 第13卷 第5期 doi: 10.1007/s11783-019-1152-1

摘要： The wastewater from industrial area was treated by EC via Fe and Al electrodes. Cu, Ni, Cr and Zn were highly removed at the first minutes, simultaneously. Pseudo-2nd-order was found to be more suitable for kinetics. Adsorption capacities based on kinetic modeling were observed as Cr>Cu>Ni>Zn. The chemical cost in the case of pH adjustment after EC was less as 3.83 $/m3. It is known that wastewater produced by the metal-plating industry contains several heavy metals, which are acidic in nature and therefore toxic for the environment and for living creatures. In particular, heavy metals enter the food chain and accumulate in vital organs and cause serious illness. The precipitation of these metals is mostly achieved by pH adjustment, but as an alternative to this method, the electrocoagulation process has investigated in this study using iron and aluminum electrodes. The effects of the pH adjustment on removal before and after the electrocoagulation process were investigated, and cost analyses were also compared. It was observed that a high proportion of removal was obtained during the first minutes of the electrocoagulation process; thus, the current density did not have a great effect. In addition, the pH adjustment after the electrocoagulation process using iron electrodes, which are 10% more effective than aluminum electrodes, was found to be much more efficient than before the electrocoagulation process. In the process where kinetic modeling was applied, it was observed that the heavy metal removal mechanism was not solely due to the collapse of heavy metals at high pH values, and with this modeling, it was seen that this mechanism involved adsorption by iron and aluminum hydroxides formed during the electrocoagulation process. When comparing the ability of heavy metals to be adsorbed, the sequence was observed to be Cr>Cu>Ni>Zn, respectively.

关键词： Electrochemical treatment     Heavy metals     Kinetic modeling     Pseudo first order kinetic     Pseudo second order kinetic    

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超音速火焰喷涂WC涂层替代电镀硬铬：疲劳和摩擦磨损性能

周克崧,邓春明,刘敏

《中国工程科学》 2009年 第11卷 第10期   页码 48-54

摘要：

以WC涂层在飞机起落架的应用作为研究背景，对300 M超高强钢基体上电镀硬铬和超音速火焰喷涂WC-17Co和WC-10Co4Cr涂层的疲劳及与Al—Ni—Bronze合金的摩擦磨损性能进行了研究。结果表明，有WC涂层300 M钢的疲劳寿命与无涂层300 M钢的疲劳极限和过载下的疲劳寿命相当，WC涂层对300 M钢的疲劳寿命不会产生不良影响；而电镀硬铬使300 M钢的疲劳极限降低120 MPa，疲劳寿命则降低70 %～90 %。疲劳失效分析表明， WC涂层中的疲劳裂纹在界面上发生偏斜，转向沿界面扩展，因此对基体的疲劳寿命没有影响；而电镀硬铬中的的疲劳裂纹扩展到基体表面，显著降低基体的疲劳寿命。10#航空液压油润滑下涂层与Al—Ni—Bronze合金的摩擦磨损表明，与电镀硬铬对磨时，Al—Ni—Bronze合金发生明显的磨损，同时因质量转移而导致电镀硬铬的质量显著增加；而WC涂层仅略有失重，相应地Al—Ni—Bronze合金的失重仅为与电镀硬铬层磨损失重的1/50～1/100。WC涂层与Al—Ni—Bronze合金的磨损机理主要为磨粒磨损；电镀硬铬与Al—Ni—Bronze合金的磨损机理主要为黏着磨损。

关键词： 300 M钢     超音速火焰喷涂     WC涂层     电镀硬铬     疲劳     摩擦磨损    

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Plated contacts for solar cells with superior adhesion strength to screen printed solar cells

R. CHEN,S. WANG,A. WENHAM,Z. SHI,T. YOUNG,J. JI,M. EDWARDS,A. SUGIANTO,L. MAI,S. WENHAM,C. CHONG

《能源前沿（英文）》 2017年 第11卷 第1期   页码 72-77 doi: 10.1007/s11708-016-0428-4

摘要： The improvement of adhesion strength and durability of plated contacts is required for cell manufacturers to gain confidence for large-scale manufacturing. To overcome weak adhesion at the metal/Si interface, new approaches were developed. These involve the formation of laser-ablated anchor points, or grooves in the extreme case of overlapping anchor points, in the heavily doped silicon surface. When plated, these features greatly strengthen the mechanical adhesion strength of the metal. A stylus-based adhesion tester was developed specifically for evaluating the effectiveness of plated contacts to smooth silicon surfaces. The use of such a tester was also extended in this work to textured and roughened surfaces to allow evaluation of different metal contacting approaches. The adhesion strengths for various metal contacting schemes were evaluated, including screen-printed silver contacts, nickel/copper (Ni/Cu) light-induced plated (LIP) contacts for laser-doped selective emitter (LDSE) cells, buried-contact solar cells (BCSCs), and Ni/Cu LIP contacts formed with laser-ablated anchoring points in selective emitter (LAASE) cells. The latter has superior adhesion strength. The standard “peel test” of the industry was compared to the stylus-based adhesion testing, with the latter shown value for testing metal contacts on smooth surfaces but with caution needed for use with textured or roughened surfaces.

关键词： light-induced plating     metal adhesion strength     copper plating     metal contacts     solar cell durability     silicon solar cells    

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Preparation and performance of soft actuator based on IPMC with silver electrodes

Qi CHEN, Ke XIONG, Kan BIAN, Ning JIN, Bangfeng WANG,

《机械工程前沿（英文）》 2009年 第4卷 第4期   页码 436-440 doi: 10.1007/s11465-009-0054-5

摘要： The surface electrodes of traditional ionic polymer-metal composites (IPMC) are made of platinum. To reduce the production cost, nonprecious metals such as silver is proposed. A new approach of electroless silver plating based on chemical deposition method is adopted, getting two types of IPMCs, Pt-Ag IPMC, and Ag-Ag IPMC. The microscopic analysis, driving abilities tests, and their surface-electrode resistance analysis show that Ag and Pt particles penetrate inside Nafion membrane with gradient distribution throughout the membrane. The maximum electro-active bending deformation angles of the specimens, which are obtained under the same specimen dimension and constrains, are about 60° for Pt-Pt IPMC and Pt-Ag IPMC and 90° for the Ag-Ag IPMC, respectively, corresponding to the driving voltage of 3 V, 4 V, and 1.5 V. The surface-electrode resistance of Ag-Ag IPMC is the lowest and the most stable, which shows that the proposed approach is valid. The experiments show that the IPMC technology based on the silver electrode is feasible.

关键词： ionic polymer-metal composites (IPMC)     Nafion     intelligent material     soft actuators     electroless silver plating    

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Performance of ionic polymer-metal composite (IPMC) with different surface roughening methods

Ning JIN, Bangfeng WANG, Kan BIAN, Qi CHEN, Ke XIONG,

《机械工程前沿（英文）》 2009年 第4卷 第4期   页码 430-435 doi: 10.1007/s11465-009-0053-6

摘要： Based on permeation and double chemical reduction technology, this paper researches the manufacture of Pt-ionic polymer metal composites (IPMC) and the effect of three types of surface roughening methods on the manufacture and performance of IPMC. The roughening methods include manual polishing, sanding machine polishing, and plasma surface treatment. The appearance and scanning electron microscopy (SEM) features, electro-active deformation and surface resistance characteristics of these IPMC specimens were obtained and compared through specimen tests. The results of the tests indicate that surface roughening technology obviously influences the performance of IPMC. The uniformity and compactness of the metal deposited on the surface and inside the Nafion film are improved by improving surface roughening uniformity. However, the electro-active deformation capability and surface resistance of the specimens decrease at the same time. There is an approximate linear increase relationship between the driving voltage and the bending deformation of the IPMC specimen within a certain voltage range. Under the same specimen dimension, constraints, and driving voltage (3V), the maximum electro-active bending deformation angles of the specimens are about 60°, 45°, and 15° for manual polishing, sanding machine roughening, and plasma treatment, respectively.

关键词： ionic polymer metal composites (IPMC)     surface roughening     scanning electron microscopy (SEM) analyze     actuator     electroless plating    

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Systematic literature review on smart contracts in the construction industry: Potentials, benefits, and

《工程管理前沿（英文）》 2022年 第9卷 第2期   页码 196-213 doi: 10.1007/s42524-022-0188-2

摘要： The development of digital transformation in the construction industry has led to the increasing adoption of smart contracts. As programmable applications to automatically write, verify, and enforce transaction conditions, smart contracts can be used in different areas mainly to improve automation level, information security, and built digital environment enhancement. However, the smart contract is commonly mentioned as a blockchain appendage, while its unique connotation and value in the construction industry have not been recognized. Therefore, this study carries out a systematic review based on 81 research articles published from 2014 to 2021 on smart contract applications in construction to explore and highlight their potentials under domain-specific requirements. Results are analyzed according to research type categorization and domain codification. Eight research domains are identified, where the three most highly explored domains are contract and payment, supply chain and logistics, and information management. The integration of smart contracts with other innovative concepts and advanced technologies is analyzed. The applicability, benefits, and challenges of smart contract applications regarding different research domains are discussed.

关键词： smart contracts     blockchain     construction industry     BIM     systematic review    

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Target the neglected VOCs emission from iron and steel industry in China for air quality improvement

《环境科学与工程前沿（英文）》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1695-z

摘要：

● Haze formation in China is highly correlated with iron and steel industry.

关键词： Volatile organic compounds     Iron and steel industry     Air quality     Sinter flue gas emission    

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The Development Situation, Future and Counter Measures of Remanufacturing Industry in China

Wen-qiang Liu,Jun-yuan Mo,Cheng-kui Gu

《工程管理前沿（英文）》 2016年 第3卷 第2期   页码 123-131 doi: 10.15302/J-FEM-2016021

摘要： Currently, resource supply and demand contradiction, and over-loaded environment capacity have become a bottleneck for sustainable economic development in China. Electro-mechanical products are approaching a peak of obsolescence, and massive abandoned electro-mechanical products are causing severe environmental pollution, huge waste of resources and potential safety hazard. Remanufacturing is repairing or modifying worn mechanical products using high-tech method, which buffers the contradiction between wasting and shortage of resources, and brings industry towards a comprehensive utilization of resource and environmental protection. As a new strategic industry, remanufacturing, which is highly coherent with the development strategy of the circular economy, is still in its infancy in China. This paper analyzes the developmental trends and problems of the remanufacturing industry in China, and proposes promoting measures based on the engineering practices of remanufacturing.

关键词： remanufacturing     industry     measures     development    

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石化工业的发展与催化技术

曹湘洪

《中国工程科学》 1999年 第1卷 第3期   页码 11-15

摘要：

催化技术是石化工业发展的技术基础，本文用燕山石化公司技术进步的实例及发展中面临的问题，论述了催化技术的发展对推动石化企业技术进步的作用；同时石化工业也对催化技术的发展提出了一系列新课题：老装置的技术改造要求开发更多高性能的催化剂；清洁生产工艺要求开发环境友好催化剂；调整产品结构要求催化剂有良好的适应性；节能降耗、降低成本、增强产品竞争力要求不断降低催化剂的生产成本和改进催化剂寿命、转化率、选择性等性能。

关键词： 石化工业 催化技术    

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我国汽车工业如何迎接WTO

金履忠

《中国工程科学》 2000年 第2卷 第8期   页码 18-24

摘要：

文章指出，我国轿车工业形势严峻及其原因。为迎接WTO，要从实际出发，不同汽车类别，采取不同对策：要大力改进农用车；大力开发微型车这个现实存在的、潜在的广大市场；抓紧新型电动汽车的开发；增强国有巨型汽车企业中低档轿车的自主开发能力，提高其国际竞争力；放宽政策引进外资，发展中高档及高档轿车。使占汽车产量的绝大多数、适合广大城乡人民需要的汽车生产，掌握在有自主知识产权的民族工业手里。

关键词： 汽车工业     迎接WTO     对策    

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Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

《能源前沿（英文）》 2023年 第17卷 第3期   页码 320-323 doi: 10.1007/s11708-023-0889-1

摘要： Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

关键词： materials systems    

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信息服务业支撑制造业发展策略研究

尹晓倩,辛勇飞,肖荣美

《中国工程科学》 2015年 第17卷 第7期   页码 127-126

摘要：

中国共产党第十七次全国代表大会强调我国要大力推进信息化与工业化融合，中国共产党第十八次全国代表大会报告在论述“四化”同步发展时，首先提出要“推动信息化和工业化深度融合”，国务院印发的《中国制造2025》明确提出打造具有国际竞争力的制造业。本文正是基于“两化”融合的视角，以实现国际一流制造业水平为发展目标，分析信息服务业在制造业和价值链上各环节的支撑情况，通过案例分析和企业调研等考察提出在融合发展过程中面临的信息基础设施薄弱、企业创新意识落后等诸多问题及挑战，据此提出面向制造业发展的信息服务业的发展策略。

关键词： 信息服务业     制造业     互联网     《中国制造2025》     两化融合    

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自主创新 技术学习与产业竞争力的提高——以台湾IC业为例

卢 锐,盛昭瀚

《中国工程科学》 2007年 第9卷 第8期   页码 35-39

摘要：

自主创新、技术学习是台湾集成电路（IC）产业遵循比较优势的产业政策和技术政策的结果，是基于本土市场的自主创新以及企业在 技术学习上的努力，是发展中国家的企业能够在开放市场条件下获得竞争优势的原因。

关键词： 技术学习     自主创新     产业竞争力     IC产业    

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制造业创新驱动发展战略

“制造业创新驱动发展战略研究”课题组

《中国工程科学》 2015年 第17卷 第7期   页码 20-23

摘要：

制造业是科技创新的主要载体，科技创新是制造业发展的主要力量。改革开放以来，我国制造业实现了快速增长，已成为全球制造业大国，但总体上仍然“大而不强”。科学分析我国制造业面临的发展环境、创新能力现状，实现我国制造业创新驱动发展，就是要坚持“自主创新，智能引领，绿色发展，重点突破”的指导方针，以全面提升自主创新能力为核心，以发展数字化、网络化、智能化制造为主线，以发展资源节约、环境友好的绿色制造为重要方向，率先实现重点领域重大产品和重大制造技术的突破，全面推进制造业转型升级，实现我国制造业由大到强的历史跨越。

关键词： 制造业；创新驱动；智能制造；绿色制造；“四基”；重点产业    

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标题 作者 时间 类型 操作

Efficient removal of heavy metals from electroplating wastewater using polymer ligands

Md. Lutfor RAHMAN,Shaheen M. SARKAR,Mashitah Mohd YUSOFF

期刊论文

Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy

Fatih Ilhan, Kubra Ulucan-Altuntas, Yasar Avsar, Ugur Kurt, Arslan Saral

期刊论文

超音速火焰喷涂WC涂层替代电镀硬铬：疲劳和摩擦磨损性能

周克崧,邓春明,刘敏

期刊论文

Plated contacts for solar cells with superior adhesion strength to screen printed solar cells

R. CHEN,S. WANG,A. WENHAM,Z. SHI,T. YOUNG,J. JI,M. EDWARDS,A. SUGIANTO,L. MAI,S. WENHAM,C. CHONG

期刊论文

Preparation and performance of soft actuator based on IPMC with silver electrodes

Qi CHEN, Ke XIONG, Kan BIAN, Ning JIN, Bangfeng WANG,

期刊论文

Performance of ionic polymer-metal composite (IPMC) with different surface roughening methods

Ning JIN, Bangfeng WANG, Kan BIAN, Qi CHEN, Ke XIONG,

期刊论文

Systematic literature review on smart contracts in the construction industry: Potentials, benefits, and

期刊论文

Target the neglected VOCs emission from iron and steel industry in China for air quality improvement

期刊论文

The Development Situation, Future and Counter Measures of Remanufacturing Industry in China

Wen-qiang Liu,Jun-yuan Mo,Cheng-kui Gu

期刊论文

石化工业的发展与催化技术

曹湘洪

期刊论文

我国汽车工业如何迎接WTO

金履忠

期刊论文

Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

期刊论文

信息服务业支撑制造业发展策略研究

尹晓倩,辛勇飞,肖荣美

期刊论文

自主创新 技术学习与产业竞争力的提高——以台湾IC业为例

卢 锐,盛昭瀚

期刊论文

制造业创新驱动发展战略

“制造业创新驱动发展战略研究”课题组

期刊论文